Università degli Studi di Urbino Carlo Bo / Portale Web di Ateneo


ORGANIC CHEMISTRY
CHIMICA ORGANICA

A.Y. Credits
2015/2016 8
Lecturer Email Office hours for students
Stefania Santeusanio

Assigned to the Degree Course

Giorno Orario Aula

Learning Objectives

Represent and illustrate the electronic and structural features of organic molecules; Assign correctly IUPAC names to organic molecules. Sorting the organic molecules according to the functional groups and, based on these, know their typical reactivity. Know the main reactions focusing on the mechanistic details that allow the interconversion of functional groups. Identify appropriate strategies for solving problems in order to rework the main concepts covered.

Program

1. Foundational concepts of organic chemistry
1.2. Atomic structure
1.3. Electronegativity
1..Bonding
1.5. Electron dot structures and 3D representation of organic molecules
1.6. Acids and bases
1.7. Resonance and inductive effects
2. Introduction to functional groups: structure and nomenclature
2.1. Introduction to reactions: types and symbolism to be used
3. Alkanes and Cycloalcanes: conformations
4. Stereochemistry: enantiomers, optical activity, configurations, R, S notational system, diastereomers
5. Alkenes and Dienes: structure and reactivity
6. Alkynes: structure and reactivity
7. Haloalkanes as models of nucleophilic substitution and of elimination reactions. Mechanistic insights
Preparation of Grignard reagents and their uses
8. Alcohols, ethers and epoxides: preparation and their use
9. Aromaticity and aromatic compounds: naming conventions. 9.1. Mechanism of the electrophilic aromatic substitution: alogenation, sulfonation, nitration, Friedel-Crafts alkylation and acylation, their restrictions and applications.
9.2 Aromatic nucleophilic substitutions: restrictions and applications
10. Aldehydes and ketones: methods of preparation and reactivity. Nucleophilic addition, oxidation. Keto-enol tautomerism
11. Carboxylic acids: properties, acid chloride formation, Fischer esterification
11.1 Carboxylic acid derivatives: their syntheses and reactions
12. Overview of enolate reactions
13. Amines: types, naming conventions, general properties. Preparation and reactivity.
14. Discussion and resolution of exercises

Learning Achievements (Dublin Descriptors)

The student must show knowledge and understanding of organic reactions required to produce synthetic processes of complex molecules.
The student must show to apply their knowledge, understanding and ability to solve problems in topics related to the behavior of organic substances included in a general context and will be able to communicate clearly with a chemical language adapted his conclusions, and the knowledge to specialist and non-specialist. The student will have developed those learning skills as they will be prerequisites for future teaching programs.

Teaching Material

The teaching material prepared by the lecturer in addition to recommended textbooks (such as for instance slides, lecture notes, exercises, bibliography) and communications from the lecturer specific to the course can be found inside the Moodle platform › blended.uniurb.it

Didactics, Attendance, Course Books and Assessment

Didactics

Lectures using slides; exercises

Course books

• Lectures notes, PDF copy of slides and
recommended books:
J. McMurry CHIMICA ORGANICA un approccio biologico ZANICHELLI
J. G. Smith FONDAMENTI DI CHIMICA ORGANICA McGRAW-HILL
For exercises:
T. W. Graham Solomons, G. B. Fryhle, R. G. Johnson LA CHIMICA ORGANICA ATTRAVERSO GLI ESERCIZI ZANICHELLI

Assessment

Written test for admission to the oral test

Additional Information for Non-Attending Students

Course books

• PDF copy of slides and
recommended books
J. McMurry CHIMICA ORGANICA un approccio biologico ZANICHELLI
J. G. Smith FONDAMENTI DI CHIMICA ORGANICA McGRAW-HILL
For exercises::
T. W. Graham Solomons, G. B. Fryhle, R. G. Johnson LA CHIMICA ORGANICA ATTRAVERSO GLI ESERCIZI ZANICHELLI

Assessment

Written test for admission to the oral test

Notes

Supported course ORGANIC CHEMISTRY

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